Machine learning-assisted nitrogen-doped carbon dots for Fe<sup>3+</sup> detection in aqueous environments
Abstract: The concentration of iron ions is a crucial indicator for assessing water quality. In this study, nitrogen-doped carbon dots (NCDs) were synthesized using a microwave-assisted method with citric acid and urea as precursors, thereby establishing a fluorescence sensing platform for the detection of alkaline pH and Fe 3+ . During Fe 3+ detection, the fluorescence intensity of NCDs was specifically quenched as the concentration of Fe 3+ increased, demonstrating good linearity across the ranges of 1-10 µM and 10-100…
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The concentration of iron ions is a crucial indicator for assessing water quality. In this study, nitrogen-doped carbon dots (NCDs) were synthesized using a microwave-assisted method with citric acid and urea as precursors, thereby establishing a fluorescence sensing platform for the detection of alkaline pH and Fe 3+ .
To enhance prediction accuracy across a broad concentration range, a machine learning model was introduced to develop a high-precision quantitative analysis method for Fe 3+ . The spiked recovery rates in actual water samples ranged from 99.26% to 101.14%, with relative standard deviations below 3%.
- The concentration of iron ions is a crucial indicator for assessing water quality.
- In this study, nitrogen-doped carbon dots (NCDs) were synthesized using a microwave-assisted method with citric acid and urea as precursors, thereby establishing a fluorescence sensing platform for the detection of alkaline pH and Fe 3+ .
- During Fe 3+ detection, the fluorescence intensity of NCDs was specifically quenched as the concentration of Fe 3+ increased, demonstrating good linearity across the ranges of 1-10 µM and 10-100 µM, with a detection limit of 0.55 µM.
To enhance prediction accuracy across a broad concentration range, a machine learning model was introduced to develop a high-precision quantitative analysis method for Fe 3+ .
The rundown
During Fe 3+ detection, the fluorescence intensity of NCDs was specifically quenched as the concentration of Fe 3+ increased, demonstrating good linearity across the ranges of 1-10 µM and 10-100 µM, with a detection limit of 0.55 µM. By integrating smartphone-based image analysis, visual semi-quantitative detection of alkaline pH and Fe 3+ was achieved.
Sources
- Peer-reviewedAnalytical Methods2026-09-01
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